By Krzysztof Matyjaszewski
Offers new advancements in controlled/living radical polymerization in 3 parts: atom move radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation move (RAFT). additionally contains synthesis and characterization of many new materials.
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Extra resources for Advances in Controlled/Living Radical Polymerization
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From EPR, that such mid-chain radicals play a major role in termination during D A polymerization, but are not important during homopolymerization of the other monomers. A large fraction of mid-chain radicals would also affect Ap. Further studies are required to understand the C L dependence observed in D A polymerization. It goes without saying that termination models other than the power-law expression may be used for fitting experimental S P - P L P traces. E q 7 has been applied primarily because of its simplicity and because of the availability of a theoretically derived power-law expression for the C L dependence of tenriination rate in dilute polymer solution.
The S P - P L P experiments presented in the previous section have been carried out under such conditions. The